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https://ri.ufs.br/jspui/handle/riufs/640| Tipo de Documento: | Artigo |
| Título : | [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II) |
| Autor : | Pederzolli, Fernanda Rosi Soares Bresolin, Leandro Beck, Johannes Daniels, Jörg Oliveira, Adriano Bof de |
| Fecha de publicación : | sep-2012 |
| Resumen : | The reaction of 5-bromosalicylaldehyde thiosemicarbazone with nickel acetate tetrahydrate and pyridine yielded the title compound, [Ni(C8H6BrN3OS)(C5H5N)]. The NiII atom is four-coordinated in a square-planar environment by one deprotonated dianionic thiosemicarbazone ligand, acting in a tridentate chelating mode through N, O and S atoms forming two metalla-rings, and by one pyridine molecule. The complex molecules are linked into dimers by pairs of centrosymmetrical N-H...N interactions. In addition, molecules are connected through intermolecular Br...Br interactions [3.545 (1) A], forming chains along the b-axis direction. |
| Palabras clave : | 5-bromo-salicilaldeído Tiossemicarbazonas Acetato de níquel Piridina |
| ISSN : | 1600-5368 |
| Institución / Editorial : | International Union of Crystallography |
| Citación : | PEDERZOLLI, F. R. S. et al. [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-[kappa]3O,N1,S](pyridine-[kappa]N)nickel(II). Acta Crystallographica Section E, v. 68, n. 9, p. o1804-o1804, set. 2011. Disponível em: <http://journals.iucr.org/e/issues/2012/09/00/zl2486/index.html>. Acesso em: 15 jul. 2013. |
| License: | Creative Commons Attribution Licence |
| URI : | https://ri.ufs.br/handle/riufs/640 |
| Aparece en las colecciones: | DQI - Artigos de periódicos |
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| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| 1-5-Bromo.pdf | 580,14 kB | Adobe PDF |  Visualizar/Abrir |
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