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https://ri.ufs.br/jspui/handle/riufs/23357| Document Type: | Artigo |
| Title: | Bis{4-phenyl-1-[1-(pyridin-2-yl-jN)ethylidene]thiosemicarbazidato-j2 N1 ,S}- cadmium |
| Authors: | Fonseca, Alexandra de Souza Gervini, Vanessa Carratu Bresolin, Leandro Locatelli, Aline Oliveira, Adriano Bof de |
| Issue Date: | 2012 |
| Resumo : | The reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)2]. The CdII atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, molecules are connected through inversion centers via pairs of N—HS interactions, building a onedimensional hydrogen-bonded polymer along [011]. |
| Keywords: | Single-crystal X-ray study T = 296 K Mean (C–C) = 0.005 A˚ R factor = 0.038 WR factor = 0.080 Data-to-parameter ratio = 22.6 |
| ISSN: | 1600-5368 |
| Is part of: | Acta Crystallographica |
| Language: | eng |
| Publisher / Institution : | International Union of Crystallography |
| Citation: | FONSECA, A. S. et al. Bis{4-phenyl-1-[1-(pyridin-2-yl-jN)ethylidene]thiosemicarbazidato-j2 N1 ,S}- cadmium. Acta crystallographica, Chester, v. 68, n. 5, p. 635-636, 2012. Disponível em: https://journals.iucr.org/e/issues/2012/05/00/bt5877/index.html. Acesso em: 6 out. 2025. |
| License: | Creative Commons Atribuição 2.0 Reino unido: Inglaterra e País de Gales (CC BY 2.0 UK) |
| URI: | https://ri.ufs.br/jspui/handle/riufs/23357 |
| Appears in Collections: | DQI - Artigos de periódicos |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Bis{4-phenyl-1-[1-(pyridin-2-yl-jN)ethylidene].pdf | 410,98 kB | Adobe PDF |  View/Open |
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