1. Repositório Institucional da Universidade Federal de Sergipe - RI/UFS
2. PRODUÇÃO CIENTÍFICA
3. DQI - Departamento de Química (São Cristóvão)
4. DQI - Artigos de periódicos

Document Type:	Artigo
Title:	Crystal structure of cis-bis{4-phenyl-1- [(3R)-1,7,7-trimethyl-2-oxobicyclo [2.2.1]- heptan-3-ylidene] thiosemicarbazidatoj3 O,N1 ,S} cadmium (II) with an unknown solvent molecule
Authors:	Nogueira, Vanessa Senna Bresolin, Leandro Näther, Christian Jess, Inke Oliveira, Adriano Bof de
Issue Date:	2015
Resumo :	The reaction between the racemic mixture of the camphor-4- phenylthiosemicarbazone derivative and cadmium acetate dihydrate yielded the title compound, [Cd(C17H20N3OS)2]. The CdII ion is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting as an O,N,S-donor in a tridentate chelating mode, forming five-membered chelate rings. In the crystal, the molecules are connected via pairs of N—HS and C—HS interactions, building centrosymmetric dimers. One of the ligands is disordered in the campher unit over two sets of sites with site-occupancy factors of 0.7 and 0.3. The structure contains additional solvent molecules, which are disordered and for which no reasonable split model was found. Therefore, the data were corrected for disordered solvent using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9–18] in PLATON. Since the disordered solvents were removed by data processing, and the number of solvent entities was a suggestion only, they were not considered in the chemical formula and subsequent chemical or crystal information.
Keywords:	Crystal structure ONS-thiosemicarbazone donor Camphorthiosemicarbazone Cadmium-thiosemicarbazone complex
ISSN:	2056-9890
Is part of:	Acta Crystallographica Section E
Language:	eng
Publisher / Institution :	International Union of Crystallography
Citation:	NOGUEIRA, V. S. et al. Crystal structure of cis-bis{4-phenyl-1- [(3R)-1,7,7-trimethyl-2-oxobicyclo [2.2.1]- heptan-3-ylidene] thiosemicarbazidatoj3 O,N1 ,S} cadmium (II) with an unknown solvent molecule. Acta Crystallographica Section E, Chester, v. 71, n. 12, 2015. Disponível em: https://journals.iucr.org/e/issues/2015/12/00/is5430/index.html. Acesso em: 25 abr. 2026.
License:	Creative Commons Atribuição 2.0 Reino unido: Inglaterra e País de Gales (CC BY 2.0 UK)
Identifier:	https://doi.org/10.1107/S2056989015021428
URI:	https://ri.ufs.br/jspui/handle/riufs/25108
Appears in Collections:	DQI - Artigos de periódicos

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.