Por favor, use este identificador para citar o enlazar este ítem: https://ri.ufs.br/jspui/handle/riufs/26095
Tipo de Documento: Artigo
Título : Multiple monohydroxylation products from rac-camphor by marine fungus Botryosphaeria sp. isolated from marine alga bostrychia radicans
Autor : Jesus, Hugo César Ramos de
Jeller, Alex Haroldo
Debonsi, Hosana Maria
Alves, Pericles Barreto
Porto, André Luiz Meleiro
Fecha de publicación : 2017
Resumen: This manuscript describes the biooxidation of rac-camphor using whole cells of marine-derived fungus Botryosphaeria sp. CBMAI 1197. The main biotransformation products of this monoterpene were achieved via a hydroxylation reaction and occurred with 5 days of rac-camphor incubation. Products were identified by means of gas chromatography mass spectrometry (GC-MS) and nuclear magnetic resonance (NMR) data. The major hydroxylated products were 6-endo-hydroxycamphor, 6-exo-hydroxycamphor, 5-exo-hydroxycamphor, 5-endo-hydroxycamphor, 3-exo-hydroxycamphor and 8-hydroxycamphor. The 6-exo-hydroxycamphor was obtained through a retro-aldol reaction when 6-endo-hydroxycamphor was maintained in presence of CDCl3; this isomerization was confirmed by 1 H NMR and GC-MS data.
Palabras clave : Terpene
Hydroxylation
Biocatalysis
Marine endophytic fungi
ISSN : 1678-4790
Es parte de: Journal of the Brazilian Chemical Society
Idioma : eng
Institución / Editorial : Sociedade Brasileira de Química
Citación : JESUS, H. C. R. et al. Multiple monohydroxylation products from rac-camphor by marine fungus Botryosphaeria sp. isolated from marine alga bostrychia radicans. Journal of the Brazilian Chemical Society, São Paulo, v. 28, n. 3, p. 498–504, 2017. DOI: http://dx.doi.org/10.21577/0103-5053.20160262. Disponível em: https://www.scielo.br/j/jbchs/a/wvzCNnh6hfRw9JpgDcBbdYw/abstract/?lang=en. Acesso em: 11 set. 2026.
License: Creative Commons Atribuição 4.0 Internacional (CC BY 4.0)
Identificador: https://doi.org/10.21577/0103-5053.20160262
URI : https://ri.ufs.br/jspui/handle/riufs/26095
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