[1-(5-Bromo-2-oxidobenzylidene) thiosemicarbazidato-j3 O,N1,S] (pyridinejN) nickel (II)

Pederzolli, Fernanda Rosi Soares; Bresolin, Leandro; Beck, Johannes; Daniels, Jörg; Oliveira, Adriano Bof de

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Campo DC	Valor	Idioma
dc.contributor.author	Pederzolli, Fernanda Rosi Soares	-
dc.contributor.author	Bresolin, Leandro	-
dc.contributor.author	Beck, Johannes	-
dc.contributor.author	Daniels, Jörg	-
dc.contributor.author	Oliveira, Adriano Bof de	-
dc.date.accessioned	2025-10-13T18:58:31Z	-
dc.date.available	2025-10-13T18:58:31Z	-
dc.date.issued	2012	-
dc.identifier.citation	PEDERZOLLI, F. R. S. et al. [1-(5-Bromo-2-oxidobenzylidene) thiosemicarbazidato-j3 O,N1,S] (pyridinejN) nickel (II). Acta crystallographica Section E, Chester, v. 68, n. 9, p. m1138, 2012. Disponível em: https://journals.iucr.org/e/issues/2012/09/00/zl2486/zl2486.pdf. Acesso em: 13 out. 2025.	pt_BR
dc.identifier.issn	1600-5368	-
dc.identifier.uri	https://ri.ufs.br/jspui/handle/riufs/23446	-
dc.language	eng	pt_BR
dc.publisher	International Union of Crystallography	pt_BR
dc.relation.ispartof	Acta Crystallographica Section E	pt_BR
dc.subject	Single-crystal X-ray study	eng
dc.subject	T = 293 K	eng
dc.subject	Mean (C–C) = 0.004 A˚	eng
dc.subject	R factor = 0.031	eng
dc.subject	WR factor = 0.083	eng
dc.subject	Data-to-parameter ratio = 17.0	eng
dc.title	[1-(5-Bromo-2-oxidobenzylidene) thiosemicarbazidato-j3 O,N1,S] (pyridinejN) nickel (II)	pt_BR
dc.type	Artigo	pt_BR
dc.identifier.license	Creative Commons Atribuição 2.0 Reino unido: Inglaterra e País de Gales (CC BY 2.0 UK)	pt_BR
dc.description.resumo	The reaction of 5-bromosalicylaldehyde thiosemicarbazone with nickel acetate tetrahydrate and pyridine yielded the title compound, [Ni(C8H6BrN3OS)(C5H5N)]. The NiII atom is four-coordinated in a square-planar environment by one deprotonated dianionic thiosemicarbazone ligand, acting in a tridentate chelating mode through N, O and S atoms forming two metalla-rings, and by one pyridine molecule. The complex molecules are linked into dimers by pairs of centrosymmetrical N—HN interactions. In addition, molecules are connected through intermolecular BrBr interactions [3.545 (1) A˚ ], forming chains along the b-axis direction.	pt_BR
dc.description.local	Chester	pt_BR
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