1. Repositório Institucional da Universidade Federal de Sergipe - RI/UFS
  2. PRODUÇÃO CIENTÍFICA
  3. DQI - Departamento de Química (São Cristóvão)
  4. DQI - Artigos de periódicos
Use este identificador para citar ou linkar para este item: https://ri.ufs.br/jspui/handle/riufs/24529
Registro completo de metadados
Campo DCValorIdioma
dc.contributor.authorOliveira, Adriano Bof de-
dc.contributor.authorFeitosa, Bárbara Regina Santos-
dc.contributor.authorNäther, Christian-
dc.contributor.authorJess, Inke-
dc.date.accessioned2026-02-06T19:35:44Z-
dc.date.available2026-02-06T19:35:44Z-
dc.date.issued2014-
dc.identifier.citationOLIVEIRA, A. B. et al. Crystal structure of cis-bis [4-phenyl-2-(1,2,3,4- tetrahydronaphthalen-1-ylidene) hydrazinecarbothioamidato-j2 N1 ,S] nickel (II) monohydrate tetrahydrofuran disolvate. Acta Crystallographica Section E, Chester, v. 70, n. 8, p. 101-103, 2014. Disponível em: https://journals.iucr.org/e/issues/2014/08/00/bx2462/index.html. Acesso em: 6 fev. 2026.pt_BR
dc.identifier.issn1600-5368-
dc.identifier.urihttps://ri.ufs.br/jspui/handle/riufs/24529-
dc.languageengpt_BR
dc.publisherInternational Union of Crystallographypt_BR
dc.relation.ispartofActa Crystallographica Section Ept_BR
dc.subjectThiosemicarbazone complexeng
dc.subjectAnagostic interactionseng
dc.subjectCrystal structureeng
dc.titleCrystal structure of cis-bis [4-phenyl-2-(1,2,3,4- tetrahydronaphthalen-1-ylidene) hydrazinecarbothioamidato-j2 N1 ,S] nickel (II) monohydrate tetrahydrofuran disolvatept_BR
dc.typeArtigopt_BR
dc.identifier.licenseCreative Commons Atribuição 2.0 Reino unido: Inglaterra e País de Gales (CC BY 2.0 UK)pt_BR
dc.description.resumoThe reaction of NiII acetate tetrahydrate with the ligand 4-phenyl-2-(1,2,3,4- tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide in a 2:1 molar ratio yielded the title compound, [Ni(C16H16N3S)2]2C4H8OH2O. The deprotonated ligands act as N,S-donors, forming five-membered metallacycles with the metal ion exhibiting a cis coordination mode unusual for thiosemicarbazone complexes. The NiII ion is four-coordinated in a tetrahedrally distorted square-planar geometry. Trans-arranged anagostic C—HNi interactions are observed. In the crystal, the complex molecules are linked by water molecules through N—HO and O—HS hydrogen-bonding interactions into centrosymmetric dimers stacked along the c axis, forming rings of graph-set R4 4 (12). Classical O—HO hydrogen bonds involving the water and tetrahydrofuran solvent molecules as well as weak C—H interactions are also present.pt_BR
dc.description.localChesterpt_BR
dc.identifier.doihttps://doi.org/10.1107/S1600536814016079-
Aparece nas coleções:DQI - Artigos de periódicos

Arquivos associados a este item:
Arquivo Descrição TamanhoFormato 
CrystalStructureCisBis[4-phenyl.pdf379,65 kBAdobe PDFThumbnail
Visualizar/Abrir
Mostrar registro simples do item Visualizar estatísticas


Os itens no repositório estão protegidos por copyright, com todos os direitos reservados, salvo quando é indicado o contrário.