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Use este identificador para citar ou linkar para este item: https://ri.ufs.br/jspui/handle/riufs/24617
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dc.contributor.authorSiqueira, Diego Pereira-
dc.contributor.authorSiqueira, Maria Carolina Bulhosa-
dc.contributor.authorGervini, Vanessa Carratu-
dc.contributor.authorBresolin, Leandro-
dc.contributor.authorOliveira, Adriano Bof de-
dc.date.accessioned2026-02-23T18:56:45Z-
dc.date.available2026-02-23T18:56:45Z-
dc.date.issued2014-
dc.identifier.citationSIQUEIRA, D. P. et al. Crystal structure of bis {l-4-methyl-N0-[3- (oxidoimino) butan-2-ylidene] benzenesulfonohydrazidato} bis [(dimethyl sulfoxide-jO) copper (II)]. Acta Crystallographica Section E, Chester, v. 70, n. 9, 2014. Disponível em: https://journals.iucr.org/e/issues/2014/09/00/xu5805/index.html. Acesso em: 23 fev. 2026.pt_BR
dc.identifier.issn1600-5368-
dc.identifier.urihttps://ri.ufs.br/jspui/handle/riufs/24617-
dc.languageengpt_BR
dc.publisherInternational Union of Crystallographypt_BR
dc.relation.ispartofActa Crystallographica Section Ept_BR
dc.subjectCrystal structureeng
dc.subjectHydroxyimino-tosylhydrazone derivativeeng
dc.subjectCuII dimereng
dc.subjectStackingeng
dc.titleCrystal structure of bis {l-4-methyl-N0-[3- (oxidoimino) butan-2-ylidene] benzenesulfonohydrazidato} bis [(dimethyl sulfoxide-jO) copper (II)]pt_BR
dc.typeArtigopt_BR
dc.identifier.licenseCreative Commons Atribuição 2.0 Reino unido: Inglaterra e País de Gales (CC BY 2.0 UK)pt_BR
dc.description.resumoIn the title compound, [Cu2(C11H13N3O3S)2(C2H6OS)2], the CuII cation is N, N0 ,O-chelated by a deprotonated hydroxyimino-tosylhydrazone ligand and coordinated by a dimethyl sulfoxide molecule. One O atom from the adjacent hydroxyimino-tosylhydrazone ligand bridges the CuII cation, forming the centrosymmetric dimeric complex. The cation is in an overall distorted N2O3 square-pyramidal coordination environment. The methylbenzene ring is twisted with respect to the hydrazine fragment, with a dihedral angle of 89.54 (9) between the planes. An intramolecular C—HO hydrogen bond occurs. In the crystal, molecules are linked by weak C— HO and C—HS interactions. Weak – stacking is also observed between parallel benzene rings of adjacent molecules, the centroid–centroid distance being 3.9592 (17) A˚ .pt_BR
dc.description.localChesterpt_BR
dc.identifier.doihttps://doi.org/10.1107/S1600536814016651-
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