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dc.contributor.authorSantos, Ivory Marcos Gomes dos-
dc.contributor.authorBarbosa, Larissa Souza Noel Simas-
dc.contributor.authorResende, Cristiane Xavier-
dc.contributor.authorSoares, Glória de Almeida-
dc.contributor.authorSantos, Euler Araujo dos-
dc.date.accessioned2026-03-13T17:47:04Z-
dc.date.available2026-03-13T17:47:04Z-
dc.date.issued2015-
dc.identifier.citationSANTOS, I. M. G. et al. Crystallographic aspects regarding the insertion of Ag+ ions into a hydroxyapatite structure. Materials Research, São Carlos, v. 18, n. 4, p. 881–890, 2015. Disponível em: https://www.scielo.br/j/mr/a/HMpbcPsdvn7qFGwB9yc8jcR/?lang=en. Acesso em: 13 mar. 2026.pt_BR
dc.identifier.issn1980-5373-
dc.identifier.urihttps://ri.ufs.br/jspui/handle/riufs/24777-
dc.languageengpt_BR
dc.publisherAssociação Brasileira de Metalurgia, Materiais e Mineração (ABM) / Associação Brasileira de Cerâmica (ABC) / Associação Brasileira de Polímeros (ABPol)pt_BR
dc.relation.ispartofMaterials Researchpt_BR
dc.subjectHydroxyapatiteeng
dc.subjectSilvereng
dc.subjectDopingeng
dc.subjectCarbonateeng
dc.subjectDiffusioneng
dc.titleCrystallographic aspects regarding the insertion of Ag+ ions into a hydroxyapatite structurept_BR
dc.typeArtigopt_BR
dc.identifier.licenseCreative Commons Atribuição 4.0 Internacional (CC BY 4.0)pt_BR
dc.description.resumoThe objective of this study was to evaluate how silver can be inserted into hydroxyapatite (HA) via two distinct processes: co-doping with CO32- via precipitation in an aqueous medium and immersion of preformed HA crystals into Ag+ solutions. It was concluded that although Ag+ and Ca2+ have different radii, the accommodation of Ag+ ions in the Ca2+ sites of the hydroxyapatite lattice can be explained by the models proposed for inserting monovalent ions such as Na+. In this case, because Ag+ ions are larger than Ca2+ ions and have a different charge, the Ag+ ions are stabilized in the HA structure by co-substitution with CO32- ions in both the A- and B-type sites. This simultaneous insertion of Ag+ and CO32- appears to thermally stabilize the HA phase because no phase transformation is observed after calcination. In addition, the doping of HA with Ag+ ions can clearly occur via two routes: co-precipitation in the presence of these ions or diffusion in preformed hydroxyapatite crystals. This result appears to indicate the possibility of doping HA with Ag+ using less complex routes at ambient temperature and with prefabricated implants or biomaterials, which reduces the costs of producing devices with antibacterial effects.pt_BR
dc.description.localSão Carlospt_BR
dc.identifier.doihttps://doi.org/10.1590/1516-1439.012515-
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