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dc.contributor.authorSantana, Genelane Cruz-
dc.contributor.authorGimenez, Iara de Fátima-
dc.contributor.authorNäther, Christian-
dc.contributor.authorJess, Inke-
dc.contributor.authorOliveira, Adriano Bof de-
dc.date.accessioned2026-07-06T18:33:59Z-
dc.date.available2026-07-06T18:33:59Z-
dc.date.issued2015-
dc.identifier.citationSANTANA, G. C. et al. Crystal structure of bis[N-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene) hydrazinecarbothioamidato-j2 N2 ,S] zinc dimethyl sulfoxide monosolvate. Acta Crystallographica Section E, Chester, v. 71, n. 5, 2015. Disponível em: https://journals.iucr.org/e/issues/2015/05/00/im2462/index.html. Acesso em: 30 abr. 2026.pt_BR
dc.identifier.issn2056-9890-
dc.identifier.urihttps://ri.ufs.br/jspui/handle/riufs/25123-
dc.languageengpt_BR
dc.publisherInternational Union of Crystallographypt_BR
dc.relation.ispartofActa Crystallographica Section Ept_BR
dc.subjectCrystal structureeng
dc.subjectThiosemicarbazone–ZnII complexeng
dc.subjectHydrogen-bonded polymereng
dc.titleCrystal structure of bis[N-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene) hydrazinecarbothioamidato-j2 N2 ,S] zinc dimethyl sulfoxide monosolvatept_BR
dc.typeArtigopt_BR
dc.identifier.licenseCreative Commons Atribuição 2.0 Reino unido: Inglaterra e País de Gales (CC BY 2.0 UK)pt_BR
dc.description.resumoThe reaction of the N-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide ligand with zinc acetate dihydrate in a 2:1 molar ratio yielded a yellow solid, which was crystallized from DMSO to obtain the title compound, [Zn(C17H16N3S)2]C2H6OS. The ZnII ion is four-coordinated in a distorted tetrahedral environment by two deprotonated ligands. Each ligand acts as an N,S-donor, forming a five-membered metallacycle. The maximum deviation from the mean plane of the N–N–C–S chelate group is 0.0029 (14) A˚ for the N-donor atom of one ligand and 0.0044 (14) A˚ for the non-coordinating N atom of the second. The dihedral angle between the planes of the two chelate groups is 72.80 (07). Bond lengths in the ligands are compared with those in the crystal structure of the free ligand. In the crystal, complex molecules are connected by dimethyl sulfoxide solvate molecules via N—HO hydrogenbonding interactions, building a one-dimensional hydrogen-bonded polymer along the a-axis direction. The S atom and one C atom of the dimethyl sulfoxide solvate molecules are disordered over two sets of sites with an occupancy ratio of 0.6:0.4.pt_BR
dc.description.localChesterpt_BR
dc.identifier.doihttps://doi.org/10.1107/S205698901500612X-
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