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Document Type: Artigo
Title: [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato-3O,N1,S](pyridine-N)nickel(II)
Authors: Pederzolli, Fernanda Rosi Soares
Bresolin, Leandro
Beck, Johannes
Daniels, Jörg
Oliveira, Adriano Bof de
Issue Date: Sep-2012
Abstract: The reaction of 5-bromosalicylaldehyde thiosemicarbazone with nickel acetate tetrahydrate and pyridine yielded the title compound, [Ni(C8H6BrN3OS)(C5H5N)]. The NiII atom is four-coordinated in a square-planar environment by one deprotonated dianionic thiosemicarbazone ligand, acting in a tridentate chelating mode through N, O and S atoms forming two metalla-rings, and by one pyridine molecule. The complex molecules are linked into dimers by pairs of centrosymmetrical N-HN interactions. In addition, molecules are connected through intermolecular BrBr interactions [3.545 (1) Å], forming chains along the b-axis direction.
Keywords: 5-bromo-salicilaldeído
Acetato de níquel
ISSN: 1600-5368
Publisher / Institution : International Union of Crystallography
Citation: PEDERZOLLI, F. R. S. et al. [1-(5-Bromo-2-oxidobenzylidene)thiosemicarbazidato- , , ](pyridine- )nickel(II). Acta Crystallographica Section E, Chester, v. 68, p. m1138-m1138, set. 2012. Disponível em: <>. Acesso em: 12 jul. 2013.
License: Creative Commons Attribution Licence
Appears in Collections:DQI - Artigos de periódicos

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