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Use este identificador para citar ou linkar para este item: https://ri.ufs.br/jspui/handle/riufs/25108
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dc.contributor.authorNogueira, Vanessa Senna-
dc.contributor.authorBresolin, Leandro-
dc.contributor.authorNäther, Christian-
dc.contributor.authorJess, Inke-
dc.contributor.authorOliveira, Adriano Bof de-
dc.date.accessioned2026-07-06T18:30:37Z-
dc.date.available2026-07-06T18:30:37Z-
dc.date.issued2015-
dc.identifier.citationNOGUEIRA, V. S. et al. Crystal structure of cis-bis{4-phenyl-1- [(3R)-1,7,7-trimethyl-2-oxobicyclo [2.2.1]- heptan-3-ylidene] thiosemicarbazidatoj3 O,N1 ,S} cadmium (II) with an unknown solvent molecule. Acta Crystallographica Section E, Chester, v. 71, n. 12, 2015. Disponível em: https://journals.iucr.org/e/issues/2015/12/00/is5430/index.html. Acesso em: 25 abr. 2026.pt_BR
dc.identifier.issn2056-9890-
dc.identifier.urihttps://ri.ufs.br/jspui/handle/riufs/25108-
dc.languageengpt_BR
dc.publisherInternational Union of Crystallographypt_BR
dc.relation.ispartofActa Crystallographica Section Ept_BR
dc.subjectCrystal structureeng
dc.subjectONS-thiosemicarbazone donoreng
dc.subjectCamphorthiosemicarbazoneeng
dc.subjectCadmium-thiosemicarbazone complexeng
dc.titleCrystal structure of cis-bis{4-phenyl-1- [(3R)-1,7,7-trimethyl-2-oxobicyclo [2.2.1]- heptan-3-ylidene] thiosemicarbazidatoj3 O,N1 ,S} cadmium (II) with an unknown solvent moleculept_BR
dc.typeArtigopt_BR
dc.identifier.licenseCreative Commons Atribuição 2.0 Reino unido: Inglaterra e País de Gales (CC BY 2.0 UK)pt_BR
dc.description.resumoThe reaction between the racemic mixture of the camphor-4- phenylthiosemicarbazone derivative and cadmium acetate dihydrate yielded the title compound, [Cd(C17H20N3OS)2]. The CdII ion is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting as an O,N,S-donor in a tridentate chelating mode, forming five-membered chelate rings. In the crystal, the molecules are connected via pairs of N—HS and C—HS interactions, building centrosymmetric dimers. One of the ligands is disordered in the campher unit over two sets of sites with site-occupancy factors of 0.7 and 0.3. The structure contains additional solvent molecules, which are disordered and for which no reasonable split model was found. Therefore, the data were corrected for disordered solvent using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9–18] in PLATON. Since the disordered solvents were removed by data processing, and the number of solvent entities was a suggestion only, they were not considered in the chemical formula and subsequent chemical or crystal information.pt_BR
dc.description.localChesterpt_BR
dc.identifier.doihttps://doi.org/10.1107/S2056989015021428-
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