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Document Type: | Artigo |
Title: | The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1) |
Authors: | Oliveira, Adriano Bof de Beck, Johannes Daniels, Jörg Santos, Jaciara Nascimento Feitosa, Bárbara Regina Santos |
Issue Date: | Feb-2013 |
Abstract: | The reaction of 1-aminoanthraquinone with 7,7',8,8'-tetracyanoquinodimethane yielded the title charge-transfer complex, C14H9NO2·C12H4N4. The molecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyano N atom, respectively. The dihedral angle between the two planes is 3.55 (3)°. In the crystal, molecules are stacked into columns along the a-axis direction. Pairs of N-HN and N-HO interactions connect the molecules perpendicular to the stacking direction. Additionally, an intramolecular N-HO hydrogen-bond interaction is observed for 1-aminoanthraquinone. |
Keywords: | Complexo de transferência de carga 1-Aminoanthraquinone C14H9NO2·C12H4N4. |
ISSN: | 1600-5368 |
Publisher / Institution : | International Union of Crystallography |
Citation: | OLIVEIRA, A. B. et al. The charge-transfer complex 1-aminoanthraquinone-7,7',8,8'-tetracyanoquinodimethane (1/1). Acta Crystallographica Section E, Chester, v. 69, n. 2, p. o301-o301, fev. 2013. Disponível em: <http://journals.iucr.org/e/issues/2013/02/00/bt6884/index.html>. Acesso em: 12 jul. 2013. |
License: | Creative Commons Attribution Licence |
URI: | https://ri.ufs.br/handle/riufs/636 |
Appears in Collections: | DQI - Artigos de periódicos |
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Charge-TransferComplex.pdf | 562,77 kB | Adobe PDF | ![]() View/Open |
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